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Oxidation Flocculation Reaction (OFR) Technology

Addressing The Problem

Water, as the foundation of all life, faces increasing challenges due to the growing global population, leading to heightened water usage and daily wastewater disposal. Governments strive to save lives and preserve water resources through innovative methods. Addressing water scarcity and contamination requires effective wastewater treatment and reuse. Different types of wastewater, such as household, hospital, food industry, metal industry, and painting industry effluents, demand specific treatment processes.


Various methods exist for wastewater treatment, encompassing physical, biological, and chemical approaches. Physical treatment methods like temperature control, oil separation, and large particulate physical separation are popular. Biological treatment, while effective for traditional municipal wastewater, proves inadequate for industrial effluents resistant to biodegradation. Chemical treatments, including adsorption, advanced oxidation processes (AOPs), coagulation-flocculation, and nanotechnology, play a crucial role.


Among AOPs, the Oxidation Flocculation Reaction (OFR) stands out for efficiently removing dangerous organic pollutants. Hydroxyl radicals (OH•) generated during this process serve as a potent source of oxidation energy with minimal waste production. Factors influencing chemical oxidation include pH, hydrogen peroxide (H2O2) dose, ferrous sulfate (FeSO4.7H2O) dose, time, and initial concentration. Experimental results demonstrate the OFR process's effectiveness, achieving elimination rates exceeding 95%. OFR's unique combination of oxidation and flocculation reactions contributes to the breakdown of organic contaminants

What is OFR?

The patented Hydroxyl Treatment technology represents a highly effective solution for the removal of ammonia, COD, BOD, and diverse organic and industrial wastes. Through selective catalytic oxidation, pollutants are transformed into carbon dioxide, water, and smaller ions. This system, comprising a low-voltage electrode array and proprietary packing, offers a stable, straightforward, and adaptable approach for efficient pollutant removal across varying concentrations. Its three-dimensional electrolytic effect underscores its efficacy in addressing complex wastewater challenges with a professional and innovative approach.

The OFR system consists of the following three main components:

  1. Static Hydro Reactor (SHR) 
  2. Dynamic Hydro Reactor (DHR) 
  3. The Labyrinth Clarifier (LC)  

OFR Benefits

  • Low CAPEX & Low OPEX: OFR technology offers cost-effective solutions with reduced capital and operational expenses.
  • High Efficiency: Demonstrates a high level of efficacy in treating wastewater, ensuring optimal pollutant removal.
  • Low Area Requirement: Requires minimal space for installation, making it suitable for applications with limited available area.
  • Low Energy Consumption: Operates with energy efficiency, contributing to overall sustainability and reduced operational costs.
  • Superior Outlet Quality: Provides treated water of high quality, meeting stringent standards for discharge or reuse.
  • Handles Difficult Waste: Effectively addresses challenging wastewater compositions, including industrial and complex domestic effluents.
  • Low Sludge Production: Minimizes sludge generation, simplifying disposal and reducing associated environmental impacts.

OFR Treating Hard COD

The pivotal strength of OFR Technology lies in its unique capacity to convert refractory and toxic Chemical Oxygen Demand (COD) into more environmentally manageable biodegradable COD. By significantly improving the COD to Biochemical Oxygen Demand (BOD) ratio from 10 to approximately 2, OFR Technology demonstrates a profound impact on the treatment efficiency of complex wastewater.


This transformative ability positions OFR as an invaluable tool for pretreating recalcitrant wastewater, effectively rendering it amenable to subsequent treatment using conventional technologies. By mitigating the challenges posed by refractory compounds, OFR not only simplifies the treatment process but also enhances the overall efficacy of wastewater treatment facilities.


The technology's proficiency in altering the COD composition makes it a strategic asset in addressing environmental concerns associated with industrial and complex organic waste discharges. With OFR Technology at the forefront, the path to sustainable and efficient wastewater management becomes a reality, marking a significant advancement in the field of water treatment solutions.

Applications for OFR

Oxidation Flocculation Reaction (OFR) technology finds widespread application across diverse industries, including industrial, domestic, and oil and gas sectors. Its versatility lies in effectively addressing wastewater treatment challenges, demonstrating efficacy in the removal of contaminants and pollutants in various contexts. OFR's adaptability underscores its role as a valuable solution for water treatment needs in a range of industrial settings, ensuring comprehensive and efficient purification processes.


Applications:

  • Breakdown of Long Chain Hydrocarbon  
  • Dyeing and printing industries  
  • Pharmaceutical industries  
  • Tannery applications  
  • Pulp & paper mills  
  • Landfill leachates  
  • PCB production  
  • Food and Beverage 


OFR Solution Methods

  • Industrial Wastewater Treatment: Versatile solution suitable for challenging industrial wastewater applications.
  • On-Site Wastewater Treatment: Highly mobile; can be integrated onto trolleys and mobile skids for on-site treatment.
  • Reuse and Recycling: Adaptable for applications demanding the reuse and recycling of wastewater and byproducts.
  • Centralized Wastewater Treatment: Scalable; can be combined for use in centralized wastewater treatment plants.
  • Decentralized Wastewater Treatment: Modular and compact; deployable at the source in decentralized treatment plants.

 









OFR Business Solution Methods 

Static Hydro Reactor (SHR)

The patented Static Hydro Reactor (SHR) design introduced by Future Resources incorporates proprietary multi-function media known as "SHR media" and compressed air to effectively break down and treat specific pollutants in wastewater. This innovative system relies on the principle of electrochemical oxidation-reduction, commonly referred to as the Redox process, to eliminate a wide range of water pollutants.


The SHR media consists of two elements: media A, with a positive charge, and media B, with a negative charge. This unique setup leverages the Redox reaction, where positively charged impurities are attracted to media B, and negatively charged impurities are attracted to media A. When wastewater and compressed air come into contact with the SHR media, the Redox reaction occurs.


The SHR acts as a miniature electrolytic cell within the spaces between each particle, with media B acting as the anode and media A as the cathode. As impurities and contaminants pass through this electrolytic cell, metallic impurities are drawn to the surface of the SHR particles through the magnetic force created by the electrolytic cell. Simultaneously, non-metallic impurities react with the SHR, forming oxides in media B and hydroxides in media A. These byproducts remain within the wastewater, and hydroxyl radicals are generated.


As the wastewater containing these radicals passes through the labyrinth clarifier, a process is initiated wherein colloids come out of suspension, forming floc or flakes. This process is further enhanced by the addition of a clarifying agent. The result is an efficient and comprehensive treatment of wastewater, with the SHR technology effectively addressing a wide array of impurities through the Redox reaction and subsequent byproduct formation.


The design of the Static Hydro Reactor (SHR) media is specifically tailored to accomplish various crucial tasks in wastewater treatment. 


Here are the key functionalities of the SHR media:


Oxidation-Reduction Reaction: The SHR media is engineered to initiate oxidation-reduction reactions, targeting specific pollutants in wastewater. This process involves the transfer of electrons between reactants, leading to the breakdown and transformation of contaminants.


Coagulation and Absorption: The media facilitates coagulation and absorption of waste, promoting the agglomeration of pollutants. This coagulation process enhances the removal of contaminants by forming larger particles that are easier to separate from the water.


Flocculation of Pollutants: The SHR media promotes flocculation, causing the aggregation of fine particles into larger clusters or flocs. This aids in the efficient removal of pollutants from the wastewater.


Removal of Dissolved/Emulsified Mineral Oil & Grease: The SHR media effectively removes dissolved and emulsified mineral oil and grease from wastewater, addressing a common challenge in industrial and municipal wastewater streams.


Removal of Surfactants: Surfactants, including detergents, soaps, and raw materials from cosmetics, are targeted by the SHR media for removal. This is essential for improving water quality and ensuring compliance with environmental standards.


Removal of Solvents: The SHR media is designed to remove solvent pollutants present in wastewater. This is crucial for mitigating the environmental impact of industrial discharges.


Removal of Heavy Metals: The SHR media exhibits the capability to efficiently remove heavy metals from wastewater, contributing to the reduction of toxic substances and potential environmental harm.


Removal of Aromatic Compounds: Aromatic compounds, such as benzene, ethyl-benzene, and xylene, are effectively targeted and removed by the SHR media. This enhances the overall treatment efficiency by addressing a broad spectrum of organic contaminants.


The comprehensive design of the SHR media showcases its versatility in addressing diverse pollutants, making it a valuable component in wastewater treatment processes.


Key Advantages of SHR:


The implementation of the Static Hydro Reactor (SHR) technology offers a multitude of advantages, making it a highly effective and efficient solution for wastewater treatment.


High Treatment Efficiency: The SHR technology demonstrates high treatment efficiency, effectively addressing a wide range of pollutants through its unique oxidation-reduction reactions and pollutant removal mechanisms.


Stable Outlet Water Quality: The treated water consistently maintains stable and high-quality standards, meeting regulatory requirements and environmental standards.


Minimum Floor Space: The design of SHR allows for efficient space utilization, requiring minimal floor space. This is particularly beneficial for facilities with spatial constraints.


Low Cost of Ownership: The overall cost of ownership is minimized due to the system's efficiency in treating wastewater, reducing the need for additional equipment or complex infrastructure.


Low Cost of Operation and Maintenance: Operating costs are kept low, and maintenance requirements are minimal. This results in ongoing savings for the facility over the system's life cycle.


Able to Treat a Wide Variety of Wastewater: The versatility of SHR allows it to treat a diverse range of wastewater types, making it applicable across various industrial and municipal settings.


Long Operational Life: The unit has a long operational life, providing a durable and reliable solution for wastewater treatment over an extended period.


Minimum Maintenance Requirements: The SHR system requires minimal maintenance, reducing downtime and associated costs. Regular cleaning or replacement of media materials is straightforward.


Media Materials Not Consumed: The media materials used in the SHR process are not consumed during reactions, contributing to cost-effectiveness. While periodic cleaning or replacement may be necessary, the materials have a prolonged lifespan.


The combination of these advantages positions the SHR technology as a practical and sustainable choice for wastewater treatment, offering both economic and environmental benefits to industries and municipalities. 

Static Hydro Reactor (SHR) Images

Dynamic Hydro Reactor (DHR)

The Dynamic Hydro Reactor (DHR) emerges as an efficient and cost-effective solution tailored for the treatment of high-concentration pollutants in wastewater. Comprising a low-voltage (DC 24 or below) electrode array and proprietary carbon-based media, the DHR orchestrates a three-dimensional electrolytic and catalytic oxidation process.


Key features and mechanisms of the DHR technology include:


  • Unique Carbon-Based Materials and Catalysts: The DHR employs specially designed, proprietary carbon-based materials, catalysts, and auxiliary components strategically positioned between the main electrodes. This configuration enhances the system's effectiveness in pollutant removal.


  • Versatile Mixed Media: Specially selected mixed media are packed into the compact DHR structure, adapted to the type of pollutants and their properties. Under specific operating conditions, these media generate primary flocculate and oxidizing agents.


  • Physico-Chemical Reactions: The DHR induces physico-chemical reactions, including coagulation, flocculation, absorption, and catalytic oxido-decomposition reactions. These reactions work synergistically to rapidly remove pollutants from wastewater.


  • Oxidation of Hydroxyl Radicals (OH): The DHR's pollutant removal mechanism involves the oxidation of hydroxyl radicals (OH), which are produced from the nascent state H2O2 generated during the treatment process. This oxidative power transforms pollutants into carbon dioxide, water, and smaller organic and inorganic ions.


  • Low Current Consumption: With a minimal current requirement, the DHR stands out as a highly cost-effective method for generating oxidative power, contributing to its economic efficiency.


  • Potential for Digital Control System: The DHR holds the potential for evolving into a fully digital control system. This capability allows real-time monitoring and control of parameters such as ammonia levels, showcasing adaptability and precision.


The DHR technology, with its innovative design and efficient processes, demonstrates not only the capability to treat high-concentration pollutants effectively but also the potential for advancements in digital control and monitoring. As a result, the DHR represents a promising solution for wastewater treatment, emphasizing cost-effectiveness and versatility.


The DHR is highly effective in removing organic and inorganic pollutants with low power consumption and low operating cost. 


Such As:

  • Breakdown of Long Chain Hydrocarbon 
  • Removal of Soluble COD (non biodegradable) 
  • Removal of Cyanide 
  • Removal of Pesticide 
  • Removal of Dioxin 
  • Removal of Ammonia 
  • Disinfection etc. 



DHR Limitations:  

Pre-treatment is require for oil, fats and grease applications. 

Not ideal for use in very high salinity (>10%) since most energy will be wasted for heat.


Low operating cost:

 

  • Minimal Maintenance Requirements: The DHR system is designed with an emphasis on durability and longevity, requiring very little maintenance. This feature reduces downtime, operational disruptions, and associated costs, contributing to overall efficiency.
  • Low Electrical Costs: The electrical cost associated with the DHR system is minimal. With a voltage requirement of less than 50V, the system operates efficiently with low power consumption. This characteristic not only reduces operational expenses but also contributes to the system's cost-effectiveness.
  • Robust System Design: The DHR system is engineered to be robust, ensuring stability and reliability in its operation. The system's design takes into account the challenges posed by high concentrations of pollutants and chemical waste in wastewater, providing a resilient solution for diverse applications.
  • Simple Operation: Operating the DHR system is straightforward due to its simplicity and efficiency. The system is designed to be user-friendly, allowing operators to easily manage and monitor the treatment process. This simplicity contributes to overall system reliability and ease of integration into various wastewater treatment setups.



Applications:


The Dynamic Hydro Reactor (DHR) system presents a versatile and cost-effective solution with a wide range of applications. Its effectiveness makes it a viable alternative to ammonia stripping systems such as air stripping and chlorination. These conventional systems are known to be costly to operate and may have environmental concerns, especially as ammonia is not transformed into inert gases.


The DHR system has found successful applications in various sectors of the water industry and air purification since the 1990s. Its ability to provide efficient and environmentally friendly treatment has contributed to its widespread adoption. Moreover, the introduction of a domestic unit of the DHR for aquaculture in 2009 marked a significant milestone. This innovation revolutionized the ornamental fish industry, with thousands of units sold in more than 150 countries. The success of the domestic DHR unit in aquaculture has been recognized with numerous awards.


The adaptability of the DHR system across different industries highlights its versatility, economic efficiency, and positive environmental impact. As a result, it has become a prominent and successful technology in the global water treatment and air purification landscape, meeting the needs of diverse applications and contributing to sustainable practices.

Dynamic Hydro Reactor (DHR) Images

The Labyrinth Clarifier (LC)

 

The Labyrinth Clarifier (LC) represents a departure from standard industrial clarifiers, featuring a unique design that enhances its performance. Unlike traditional clarifiers, the LC incorporates a series of oblique plates arranged in parallel, with attached panels forming grooves and cells resembling a labyrinth.


Key features and characteristics of the LC include:


  1. Oblique Plate Arrangement: The LC utilizes oblique plates arranged in a parallel configuration, allowing for a more intricate and efficient design compared to traditional clarifiers.
  2. Labyrinth-Like Structure: Panels attached to the plates create a labyrinth-like structure, enhancing the separation process. This carefully designed structure plays a crucial role in the effective removal of suspended solids from the wastewater.
  3. Computer Modeling for Precision: The spacing of the plates and the resultant flow rates are meticulously calculated through computer modeling. This precision in design ensures optimal performance and efficiency in solid separation.
  4. Vortex Formation and Eddy Currents: As wastewater passes through the LC, the oblique plates induce the formation of eddy currents and vortexes within each cell. These vortexes play a critical role in separating suspended solids from the wastewater.
  5. Efficient Solid Removal: The LC achieves an impressive efficiency rate, with the capability to remove up to 90% of suspended solids from the wastewater. This high efficiency contributes to the overall effectiveness of the clarifier in treating industrial effluent.
  6. Sludge Collection at the Bottom: The separated solids are directed into a sludge tank located at the bottom of the clarifier. This facilitates the easy removal and disposal of the collected sludge.


The LC's innovative design, incorporating oblique plates and a labyrinth-like structure, showcases advanced engineering in wastewater treatment. Its efficiency in solid removal makes it a valuable component in industrial processes, contributing to the overall effectiveness of wastewater treatment and ensuring compliance with environmental standards.


Applications:


The upgrade to the Automatic Dewatering model with an optional operation platform represents a significant advancement in sludge management. This innovative sludge dewatering product offers several advantages over conventional methods and was originally developed for oily wastewater sludge. The Dewatering Press Model is patented as an upgrade for 24-hour automatic operation, providing a more efficient and streamlined solution for sludge handling.


Key features and advantages of the Automatic Dewatering model include:


Patented Upgrade for 24-Hour Automatic Operation: The Dewatering Press Model is equipped with a patented upgrade that enables continuous and automatic operation, ensuring efficiency and reducing the need for manual intervention.


Unique Dewatering Drum Design: The heart of the process lies in the unique design of the dewatering drum. This drum is engineered to achieve both thickening and pressing (dewatering) of the sludge in a single, compact operation. This design optimizes the dewatering process, enhancing overall performance.


Versatility for Various Sludge Types: Originally developed for oily wastewater sludge, the Automatic Dewatering model demonstrates versatility by effectively handling sludge with a solids concentration as low as 0.1%. This adaptability allows it to work with diverse wastewater processes.


Direct Processing from Wastewater: The Dewatering Press Model has the capability to take sludge directly from any wastewater process, eliminating the need for additional steps in sludge handling. This direct processing contributes to efficiency and simplicity.


High Cake Solids Content: The dewatering drum's efficiency results in the production of a cake with a solids content of over 25%. This high solids content is indicative of the effectiveness of the dewatering process in reducing the water content of the sludge.


Optional Operation Platform: The Automatic Dewatering model offers an optional operation platform, providing enhanced accessibility, ease of operation, and safety features for maintenance and monitoring.


The Automatic Dewatering model with its advanced features and continuous operation capability presents a modern and efficient solution for sludge management, meeting the demands of various wastewater treatment scenarios. Its unique design and upgrade for automatic operation contribute to improved performance, reduced labor requirements, and increased overall efficiency in sludge dewatering processes.

Dynamic Hydro Reactor (DHR) Images

Case studies on our patented OFR Technology

Case Study (Jubail Industrial City Wastewater Treatment):


Challenge: Marafiq aimed to enhance the biodegradability and overall efficiency of its existing wastewater treatment plant. The focus was on the removal of refractory wastewater ingredients from the incoming waste. By implementing targeted solutions and technologies, Marafiq sought to optimize the treatment process, making it more effective in breaking down complex and resistant compounds present in the wastewater. This initiative aligns with the broader goal of improving the environmental performance of the wastewater treatment plant and ensuring the sustainable management of water resources.


Solution: Future Resources successfully addressed the wastewater treatment challenge by implementing its patented OFR (Oxidation, Flocculation, and Reverse Osmosis) solution. This innovative approach involves a three-step process:


  • Static Hydro Reactor: In this initial phase, the wastewater undergoes treatment in a Static Hydro Reactor, where specific reactions take place to initiate the breakdown of complex compounds.


  • Dynamic Hydro Reactor: The treated wastewater then advances to the Dynamic Hydro Reactor, where further chemical and physical processes occur. This step is crucial for enhancing the degradation of refractory wastewater ingredients.


  • Labyrinth Clarifier: The final step involves the use of a Labyrinth Clarifier. This component plays a key role in separating and clarifying the treated water from any remaining impurities or particles, ensuring a high level of purity in the effluent.


Results: The successful implementation of these three steps within the OFR solution by Future Resources led to remarkable outcomes. The treatment process significantly improved the biodegradability of the wastewater and enhanced overall efficiency. This approach not only met Marafiq's goal of removing refractory wastewater ingredients but also contributed to a more sustainable and effective wastewater treatment plant.


The implementation of Future Resources' OFR (Oxidation, Flocculation, and Reverse Osmosis) technology resulted in significant improvements at the wastewater treatment plant. The power efficiency of the plant saw a notable increase, with a simultaneous reduction in power consumption by at least 23%. To optimize space utilization, an inefficient unit of the existing plant was replaced with the more efficient OFR technology.


Beyond efficiency gains, the water quality of the effluent witnessed substantial enhancements. The average Biochemical Oxygen Demand (BOD) was successfully lowered from 15 ppm to less than 8 ppm. This improvement reflects the effectiveness of the OFR solution in reducing organic pollutants, contributing to a higher quality of treated water. The successful integration of OFR technology not only addresses operational efficiency but also underscores a commitment to environmental sustainability and regulatory compliance.

 

Case Study (MODON Wastewater Treatment):


Challenge: The challenge faced by Modon involves the reception of highly toxic waste streams from local industries and factories. These wastes are beyond the capacity of regular biological treatment methods and cannot be effectively managed through conventional processes. This necessitates the development and implementation of specialized and advanced treatment solutions to address the unique and hazardous nature of the received waste, ensuring proper disposal and minimizing environmental impact.


Solution: Future Resources has successfully implemented the patented OFR solution, employing a three-step process for effective waste treatment. The first step involves the use of a Static Hydro Reactor, followed by a Dynamic Hydro Reactor in the second phase. The final step utilizes a Labyrinth Clarifier to ensure comprehensive treatment and removal of contaminants. This innovative approach addresses the challenges posed by toxic waste streams from local industries and factories, providing an advanced and efficient solution for waste management.


Results: Through the implementation of the patented OFR solution with its three-step process — Static Hydro Reactor, Dynamic Hydro Reactor, and Labyrinth Clarifier — Future Resources achieved significant improvements in waste treatment. The Chemical Oxygen Demand (COD) was successfully reduced from 12,000 ppm to less than 500 ppm. Furthermore, the ratio of Biochemical Oxygen Demand (BOD) to COD improved substantially, increasing from 0.2 to 0.6. These remarkable outcomes signify a transformative impact, rendering the waste manageable by conventional treatment methods. This success not only addresses environmental concerns but also enhances the overall efficacy and sustainability of waste management processes.

Download The OFR Brochure To Learn More!

OFR Brochure (pdf)Download
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Dammam, Saudi Arabia

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